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The co-catalyst effect of zeolites on acidic ionic liquid catalyzed one-pot conversion..

Chemical Communications ; 13 Ross J, Xiao J. Chemistry - A European Journal ;9 20 Halide-free highly-pure imidazolium triflate ionic liquids: Preparation and use in palladium-catalysed allylic alkylation. Green Chemistry ;9 10 Synlett ;24 17 New bicyclic phosphorous ligands: synthesis, structure and catalytic applications in ionic liquids.

Tetrahedron ;67 2 Efficient recycling of a chiral palladium catalytic system for asymmetric allylic substitutions in ionic liquid. Chemical Communications ;47 27 Catalyst life in imidazolium-based ionic liquids for palladium-catalysed asymmetric allylic alkylation. Dalton Transactions ;43 20 Molecular states of water in room temperature ionic liquidsElectronic Supplementary Information available. Organometallics ;33 3 Organometallic approach for the synthesis of nanostructures.

New J. Palladium nanoparticles immobilized in ionic liquid: An outstanding catalyst for the Suzuki C—C coupling. Catalysis Communications ;9 2 DOSY technique applied to palladium nanoparticles in ionic liquids. Angewandte Chemie International Edition ; ChemCatChem ;1 2 Finke RG. Foss, Jr. Georgetown University.

Marcel Dekker, Inc. ISBN: , pp 17— A new and specific mode of stabilization of metallic nanoparticles. Chemical Communications ; 28 ChemCatChem ;3 4 Mechanism of sulfur poisoning on supported noble metal catalyst? The adsorption and transformation of sulfur on palladium catalysts with different supports. Catalysis Letters ;12 Widegren J, Finke R. A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions.

Organometallics ;24 8 The induction phenomenon and catalytic deactivation of thiolate-stabilized raspberry-like polymer composites coated with gold nanoparticles. Nanoscale ;7 6 Qazi A, Sullivan A. Mesoporous silicabis ethylsulfanyl propane palladium catalysts for hydrogenation and one-pot two-step Suzuki cross-coupling followed by hydrogenation. Dalton Transactions ;40 40 Unexpected bond activations promoted by palladium nanoparticles.

Dalton Transactions ;43 24 A smart palladium catalyst in ionic liquid for tandem processes. Catalysis Communications ; Transition-metal mediated carbon—sulfur bond activation and transformations. Neouze M. About the interactions between nanoparticles and imidazolium moieties: emergence of original hybrid materials.

Journal of Materials Chemistry ;20 43 Journal of Molecular Catalysis A: Chemical ; Carbon nanotubes produced by fluidized bed catalytic CVD: first approach of the process.

Catalytic Applications of Metal Nanoparticles in Imidazolium Ionic Liquids

Chemical Engineering Science ;58 19 High catalytic efficiency of palladium nanoparticles immobilized in a polymer membrane containing poly ionic liquid in Suzuki—Miyaura cross-coupling reaction. Journal of Membrane Science ; French-Ukrainian Journal of Chemistry. User Username Password Remember me. Notifications View Subscribe. Article Tools Print this article. Indexing metadata.

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How to cite item. Finding References. Email this article Login required. Email the author Login required. Font Size. Abstract The catalyst immobilization in a liquid phase represents an attractive means to preserve high activities and selectivities, also permitting an easy recycling.

To attain this goal, organic products should be extracted in a simple way from the catalytic phase leading to metal-free target compounds; for this reason, ionic liquids exhibiting high affinity for metallic species and low affinity for low polar compounds, turn into a promising medium, in particular for the synthesis of fine chemicals. In the present Accounts, we illustrate this approach through our research involving both molecular organometallic compounds and metallic nanoparticles dispersed in an ionic liquid phase.

Keywords ionic liquids; catalysis; organometallic complexes; metallic nanoparticles; supported ionic liquid phase.


  • Research in the McIndoe Group.
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Full Text: PDF. Method of producing epoxides. GB Patent No. Tetrahedron: Asymmetry , 20 12 , Organometallics , 28 17 , Organometallics , 27 8 , Organometallics , 27 19 , Efficient heterogeneous asymmetric catalysis of the Mukaiyama aldol reaction by silica- and ionic liquid-supported lewis acid copper II complexes of bis oxazolines. Advanced Synthesis and Catalysis , 2 , Oxazoline-substituted prolinamide-based organocatalysts for the direct intermolecular aldol reaction between cyclohexanone and aromatic aldehydes.

Hexafluorophosphate - Wikipedia

European Journal of Organic Chemistry , 10 , Asymmetric hydrogenation of ketones with ruthenium complexes of rac- and enantiopure S,S -1,2-bis diphenylphosphino methyl cyclohexane: A comparative study with rac- and R -BINAP. Organometallics , 26 9 , Organometallics , 26 25 , Metal-dependent reactivity of electrophilic platinum group metal lewis acid catalysts: Competitive alkene dimerization, intramolecular friedel-crafts alkylation, and carbonyl-ene reactivity. Organometallics , 26 24 , In: Kollar, M, ed.

Modern Carbonylation Methods. Recyclable copper catalysts based on imidazolium-tagged bis oxazolines : A marked enhancement in rate and enantioselectivity for Diels-Alder reactions in ionic liquid.

Publications

Advanced Synthesis and Catalysis , 6 , Organic Letters , 9 23 , Asymmetric platinum group metal-catalyzed carbonyl-ene reactions: Carbon-carbon bond formation versus isomerization. Journal of Organic Chemistry , 71 26 , Modular synthesis of a new class of bis amino-oxazoline using palladium-catalyzed Buchwald-Hartwig amination methodology. Organometallics , 25 18 , The first insoluble polymer-bound palladium complexes of 2-pyridyldiphenylphosphine: Highly efficient catalysts for the alkoxycarbonylation of terminal alkynes.

Chemical Communications , 1 , Organometallics , 24 24 , Organometallics , 24 11 , Highly efficient asymmetric hetero-diels-alder reactions of carbonyl compounds catalyzed by Lewis acid platinum complexes of conformationally flexible NUPHOS-type diphosphines. Organometallics , 23 26 , Organometallics , 23 5 , Organometallics , 23 10 , Organic Letters , 5 21 , Marked enantioselectivity enhancements for Diels-Alder reactions in ionic liquids catalysed by platinum diphosphine complexes.

Green Chemistry , 6 1 , Polymer-supported phosphoramidites: highly efficient and recyclable catalysts for asymmetric hydrogenation of dimethylitaconate and dehydroamino acids and esters. Tetrahedron: Asymmetry , 14 11 , Ruthenium complexes of the 1,4-bis diphenylphosphino -1,3-butadiene-bridged diphosphine 1,2,3,4-Me4-NUPHOS: Solvent-dependent interconversion of four- and six-electron donor coordination and transfer hydrogenation activity. Organometallics , 22 7 , Iminophosphines: Synthesis, formation of 2,3-dihydro-1 H-benzo[1,3]azaphospholium salts and N- pyridinyl diphenylphosphinoylaniline, coordination chemistry and applications in platinum group catalyzed Suzuki coupling reactions and hydrosilylations.

Journal of Organometallic Chemistry , , Palladium complexes of 2-pyridinyl substituted 1,3-bis diphenylphosphino propane: Highly active catalysts for the room-temperature copolymerization of carbon monoxide with ethene.

Table of contents

Organometallics , 21 20 , Synthesis of a new class of 1,4-bis diphenylphosphino -1,3-butadiene bridged diphosphine, NUPHOS, via zirconium-mediated reductive coupling of alkynes and diynes: Applications in palladium-catalyzed cross-coupling reactions. Organometallics , 21 7 , Zirconium-mediated synthesis of a new class of 1,4-bis diphenylphosphino -1,3-butadiene-bridged diphosphine, NUPHOS: Highly efficient catalysts for palladium-mediated cross couplings.

Journal of the American Chemical Society , 21 , Organometallics , 19 26 , Organometallic chemistry of bi- and poly-nuclear complexes. Organometallics , 19 22 , Remarkable differences in catalyst activity and selectivity for the production of methyl propanoate versus CO-ethylene copolymer by a series of palladium complexes of related C4-bridged diphosphines. Organometallics , 19 24 , Alkenyl isomerization at a diiron centre. Selectivity for the methoxycarbonylation of ethylene versus CO-ethylene copolymerization with catalysts based on C4-bridged bidentate phosphines and phospholes.